Search results for "Geochemical modeling"
showing 3 items of 3 documents
The geochemical riddle of “low-salinity gypsum” deposits
2022
International audience; Gypsum makes up about one fifth of giant salt deposits formed by evaporation of seawater throughout Earth’s history. Although thermodynamic calculations and precipitation experiments predict that gypsum precipitates when the salinity of evaporating seawater attains about 110 g kg-1, gypsum deposits of the Mediterranean Salt Giant often bear the geochemical signature of precipitation from less saline water masses. Addressing this geochemical riddle is important because marine gypsum deposition and continental gypsum erosion affect the global carbon cycle. We investigated gypsum deposits formed in the marginal basins of the Mediterranean Sea during the Messinian Salini…
Geochemical modeling of evaporation processes on Mars: Insight from the sedimentary record at Meridiani Planum
2005
New data returned from the Mars Exploration Rover (MER) mission have revealed abundant evaporites in the sedimentary record at Meridiani Planum. A working hypothesis for Meridiani evaporite formation involves the evaporation of fluids derived from the weathering of martian basalt and subsequent diagenesis. On Earth, evaporite formation in exclusively basaltic settings is rare. However, models of the evaporation of fluids derived from experimentally weathering synthetic martian basalt provide insight into possible formation mechanisms. The thermodynamic database assembled for this investigation includes both Fe2+ and Fe3+ in Pitzer's ion interaction equations to evaluate Fe redox disequilibr…
Geochemical modeling of mixing between magmatic and hydrothermal gases: the case of Vulcano Island, Italy
1999
Abstract In this study we present a geochemical approach to model the mixing of magmatic and hydrothermal gases. Our model is based on a rigorous formulation of a perfectly dimensioned system of mass and energy balance equations. Inputs of the equation set are the H2O and CO2 content and gas emission temperature at the surface, together with some constraints gained from the chemical–physical features of the hydrothermal system. The output data give the composition of magmatic gas, mixing fractions and temperatures of gas mixtures in the mixing zone. The comparison of the emission temperature of fumarolic gases with their calculated mixing temperatures provides valuable indications on the ex…